Showing posts with label emissions. Show all posts
Showing posts with label emissions. Show all posts

Saturday, August 19, 2017

Local Odor Vocab



Curren's SCAQMD Urban Odor Dictionary

You’re looking at a smell network based on the work of UCLA post-grad named Jane Curren. She took all the words used in odor complaints in southern California, and found the source of those complaints. These odor sources can be anything from a hidden garbage dump to a local restaurant. The size of the blue nodes doesn’t indicate smelliness; it indicates more descriptors. Restaurants have more descriptors because they have 1. More people near them and 2. A greater diversity of things that smell. (I’m guessing this.) What this chart does show is the most common odor complaints in the middle of the cluster – we smell burnt things a lot. Also rotten eggs/sulfur/natural gas.

Below, Curren went further and found the specific chemical source of these smells, and I listed them below. Next time you smell something funny, check this list. (And the next time you’re in New Jersey, take a tour of the New Jersey Turnpike mobile museum of olfactory delights, you’ll smell firsthand many of the odors on this list!)

Curren's Urban Odor Lexicon
               
Descriptor                           Odorant
solvent                                 2-butanone
petroleum                          2-methyl-1-propene
pungent                               2-pentanone
sweet                                   2-pentanone
lemon                                   acetaldehyde
alcohol                                  acetaldehyde
acrid                                      acrolein
pungent                               ammonia
sweet solvent                   benzene
sweet                                   dichloromethane
decayed cabbage             ethyl mercaptan
pungent                               formaldehyde
rotten egg                           hydrogen sulfide
woody                                  m-cresol
resinous                               m-cresol
medical                                                m-cresol
woody                                  o-cresol
resinous                               o-cresol
medical                                                o-cresol
woody                                  p-cresol
resinous                               p-cresol
medical                                                p-cresol
medical                                                phenol
sweet                                   phenol
irritating                               propanal
fruity                                     propanal
empyreumatic                  pyridinec
irritating                               sulfurdioxide
aromatic                              toluenec
fishy                                      trimethylamine
pungent                               trimethylamine
sweet                                   acetone
minty                                    acetone
sweet solvent                   benzene
woody                                  cresol
resinous                               cresol
medicinal                             cresol
sour                                       dimethyl disulfide
onion                                    dimethyl disulfide
decayed cabbage             dimethyl sulfide
decayed cabbage             ethyl mercaptan
garlic                                      ethyl mercaptan
aromatic                              ethylbenzene
pungent                               formaldehyde
rotten eggs                         hydrogen sulfide
skunk                                    i-propyl mercaptan
sour                                       methyl mercaptan
garlic                                      methyl mercaptan
decayed cabbage             methyl mercaptan
skunk                                    n-butyl mercaptan
skunk                                    n-propyl mercaptan
medicinal                             phenol
sweet                                   phenol
irritating                               propanal
sweet                                   p-xylene
sharp                                     thiophene
skunk                                    thiophene
rubber                                  toluene
moth balls                           toluene
aromatic                              1,2,4-trimethylbenzene
aromatic                              1,3,5-trimethylbenzene
vinegar                                 acetic acid
sour                                       acetic acid
chemical                              acetone
sweet                                   acetone
acrid                                      acrolien
pungent                               ammonia
sweet                                   a-pinene
pine                                       a-pinene
sweet solvent                   benzene
malty                                     butanal
burnt                                     butanal
rancid                                    butyric acid
sour                                       butyric acid
perspiration                       butyric acid
fruity                                     butyl acetate
dead body                          cadaverine
disagreeable sweet        carbon disulfide
almond                                 chlorobenzene
sweet                                   chloroform
ethereal                               chloroform
pungent                               crotonaledehyde
gasoline                               decane
ethereal                               dichloromethane
sour                                       dimethyl disulfide
onion                                    dimethyl disulfide
decaying vegetation       dimethyl sulfide
aromatic                              ethylbenzene
oily                                         heptanal
musty                                   heptanal
woody                                  heptanal
fatty                                      hexanal
green                                    hexanal
rotten egg                           hydrogen sulfide
sharp                                     isopropyl benzene
aromatic                              isopropyl benzene
sharp                                     cumene
aromatic                              cumene
lemon                                   limonene
decayed cabbage             methyl mercaptan
moth balls                           naphthalene
tar                                          naphthalene
sweet                                   m-xylene
gasoline                               octane
sweet                                   o-xylene
pungent                               pentanal
sharp                                     propanal
vinegar                                 propanoic acid
sour                                       propanoic acid
sweet                                   p-xylene
solvent                                 styrene
rubber                                  styrene
sweet                                   tetrachloroethene
rubber                                  toluene
moth balls                           toluene
sweet                                   tricholoroethane
fishy                                      trimethylamine
fecal                                      valeric acid
sour                                       valeric acid
sweet                                   vinyl acetate

Suffet and Rosenfeld's Urban Odor Lexicon
*much of Curren’s work came from Suffet and Rosenfeld, so I added their leftover terms here

Descriptor                           Odorant
Coffee                                  Furfruryl Thiopropionate
earthy                                   Geosmin
musty                                   2-Methyl isoborneol
moldy                                   2,4,6-Trichloroanisole
grassy                                   Cis-3-hexen-1-ol
dead animal                       Putresine
rotten vegetable              Dimethyl Trisulfide
fishy                                      Dimethyl Amine
fishy                                      Methyl Amine
plastic                                   Methyl Methacrylate
fecal                                      Indole
manure                                  Skatole
burnt                                     Guiaicol

Primary document: Curren, J. 2012. Characterization of Odor Nuisance. UCLA.

Supporting document: Suffet, I.H., and P.E. Rosenfeld (2007). The Anatomy of Odour Wheels for Odors of Drinking Water, Wastewater, Compost and the Urban Environment, Water Science and Technology 55(5), 335-344.

Research note: The descriptor names come from the above source and supporting documents, whereas the odor causing compounds were matched against varying sources which will not be listed here; see instead the source document for those references

Friday, July 28, 2017

On Odors and Air Quality



Forget Beijing, walk down the street in New York City and you will see people wearing facemasks like it’s cool. Actually, it is kind of cool, but it is really sad when you think about it. It’s also pretty sad because these facemasks will do mostly nothing to help your exposure to air pollution. What you really want is a NIOSH-Approved N95 Particulate Filtering Facepiece Respirators.

Air quality should be a big deal at this time of year. Not sure where you’re reading this from, but here in New Jersey, or perhaps the greater Northeast, summer brings with it daily air quality alerts. This is where you can’t breathe too much during the hours of 11am and 11pm. Mostly these alerts have to do with ozone, which is good when it’s up in the air blocking UV rays, but not so good when it's at ground level being inhaled by you.

There are plenty of other pollutants in our air, and those living in a metropolitan area should know about these things. As will be repeated below, air pollution is the world’s largest single environmental health risk.

While I was reading a great article about a massive data-fueled smell map, I came across this passage, and figured it’s good enough on its own to put here, because it makes a really important distinction between odor and air pollution.

From the article “Smelly Maps: The Digital Life of Urban Smellscapes,” in their methodology section, about the air quality of streets and how it effects their data:

“The olfactory experience of a city is inevitably influenced also by the quality of the air, measured by the amount of pollutants that are emitted in the atmosphere by several human activities. It is useful to clarify the differences between air pollutants and odors. Air pollutants are chemicals that, when released into the air, pose potential harm to human and environmental health. These chemicals may or may not be detected through the human senses (McGinley, Mahin, and Pope 2000). Some air pollutants have odors (e.g., benzene has a sickly sweet odor) while others, such as carbon monoxide, cannot be detected through the senses of smell. Air pollution is the world’s largest single environmental health risk, being the cause of one in eight of the total premature global deaths, according to the World’s Health Organization.” http://www.who.int/mediacentre/news/releases/2014/air-pollution/en/

This goes on to list the handful of pollutants that are measured in cities: carbon monoxide, nitrogen oxides, ozone, particulate matter at both 10 and 2.5 micrograms, and sulfur dioxide.

Later, in another section, the authors mention this, which gives us an inkling that odor detection and air pollution detection could become good friends:

“ Barcelona is predominantly characterized by smells related to food and nature, while London is characterized by smells related to traffic emissions and waste. As The Economist puts it: “In 2013 the annual mean concentration of NO2 on Oxford street was one of the highest levels found anywhere in Europe.” (The Economist 2015).

One way to detect an area where local, point-source air pollution might be a problem is to look for areas with less nature. The authors of this study found that many odors were complementary, so that odors of “nature” were not found near odors of “emissions” (i.e., pollution)

Before closing I should mention that odors as co-pollutants can indicate pollution levels high enough to cause averse health effects. In a dissertation on the subject of urban odors, the author gives examples of a natural gas facility emitting benzene and a pig farm emitting H2S. In neither case did the pollutant itself smell, but the co-pollutants were enough to start an investigation.
-Curren, J. 2012. Characterization of Odor Nuisance. UCLA.

Notes:
McGinley, C.; Mahin, T.; and Pope, R. 2000. Elements of Successful Odor/Odour Laws. In WEF Odor/VOC 2000 Specialty Conference.
The Economist. 2015. The big smoke. Britain needs to do more to clean up its dirty air. January 10th.

Primary Source:
Quercia, Daniele, Rossano Schifanella, Luca Maria Aiello, and Kate McLean. 2015. “Smelly Maps: The Digital Life of Urban Smellscapes.” In Proceedings of the Ninth International AAAI Conference on Web and Social Media (ICWSM 2015). Palo Alto, CA: AAAI Publications. 327-336. Accessed November 28, 2016. http://www.aaai.org/ocs/index.php/ICWSM/ICWSM15/paper/view/10572.

Full pdf:

Post Script:
The Evolution of Face-mask Fashion, bjournal.co, Dec 2015.

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