Showing posts with label pollution. Show all posts
Showing posts with label pollution. Show all posts

Thursday, July 25, 2019

On Carbon Footprints and Cognitive Decline

 
We didn't always spend most of our time indoors. Some of us still don't. From a global perspective, most of us still don't. But for most of those living in the developed world, more time is spent indoors than out. Human-body-pollution is not a problem outside, where it is maximally distributed. Indoors, anything that is generated will accumulate, and unless it is exhausted abundantly, it can have adverse health effects. Even our own breath can fill the air until it reaches concentrations that actually have effects on cognition (according to this pretty good study, at least.)

I never thought of myself as a smokestack, as an incinerator burning garbage and belching toxins. But then I read a book called The Metabolism of the Anthroposphere, where I learned that half of all the matter we ingest will then leave our bodies not as solid waste and not as liquid waste. Half of everything we eat, by weight, is exhaled as carbon dioxide, and as the by-product of energy production. We burn food for energy, and emit the by-products like a tailpipe.

Cows release carbon dioxide when they breathe too, because they are also burning food to fuel their bodies. And just like coal power plants, except that their bodies are the infrastructure of our anthroposphere.

These emissions may be bad for the planet, but when humans do it, it's only a problem indoors. This hasn't been known as a problem until recently. Coincidentally, it's also a problem that has been getting worse. Then again, some of us might argue that the effect, reduced executive decision-making proficiency, is not a problem at all(!).

***
The history of fresh air vs human offgas may traverse a few threads. Sure, to this day people live in overcrowded and underventilated conditions. Sure squared, too many of us are exposed to pollutants that are magnitudes more harmful than CO2, and not just to our cognitive function but to organs and critical systems.

This is a first world problem. And that the very few of us on the planet of a swelling 7 billion can worry about lowering their high-level executive decision-making abilities, means there are a few less of us worrying about dying at 30 years old due to excessive inhalation of machine-generated combustion by-products indoors, for example.

That being said, we have made progress in limiting harmful exposures in the workplace and in the home. But we have neglected ourselves as a point source of pollution. And baked into our building practices from 1970 to 1990 (roughly) are energy efficient strategies that are really good at making sure we stay cooped up in a pool of our own breath.

So to recap, once we get rid of all the really harmful pollutants in the workplace – respirable particles, inert mineral fibers, toxic chemical vapors, biologically-active dust – we then start to consider the relatively invisible threat of carbon dioxide.

And why should we care; is it really a threat to human health? Maybe not. But it is a threat to our mental health. Being in a room that is poorly ventilated so that it contains double the amount of CO2 found outdoors (and generated by the exhaling human occupants) makes you a bit less sharp (actually a lot less sharp, see more details below). Double that even more, and people get even less sharp.

Trying to prove that anybody was ever killed by being less sharp is like trying to implicate climate change in a single heat wave. But there are some people who care about this – those whose job it is to provide facilities designed for people to think. Not to build cars or computer parts or to make perfumes, but to think. Classrooms are thought chambers. What is the most important thing people are doing in that space? Thinking.

Executive conference rooms are thought chambers. The small amount of people in that one room could be making decisions worth a lot of money. What if they could think 30% better, whatever the heck that means.

How about we should all want to think better. We should all want as much fresh air as possible indoors at all times. That doesn't come without a cost. You have to heat that outside air, or cool it, or take the water out of it, or put it back in, and filter and circulate. That all costs money, especially the heating and cooling.

How much is it worth to do one thing that would get every student to think a little bit better? How much does it cost to condition their fresh air during a cold snap or a heat wave? How much is it worth for a group of six entrepreneurs to craft a plan that's a little bit better?

It may take a while for us to reach the point where we can begin to care about these things, but this is the logical next step.

Progress will march on, and as more and more of the world spends their time indoors, (and cleans up their act so they are no longer worried about physically harmful pollutants), then more and more will be looking for the next improvement in their environment. And this is final frontier, removing our own carbon dioxide from the equation.


*Body odor is not known to be a health hazard, although the WELL Certification regimen, for assessing the health and wellness of the insides of a building, includes criteria for "Olfactory Comfort;" Designers can obtain credits for providing abundant exhaust/fresh air, or for controlling and limiting the migration of odors, problems that occur to the human occupancy of interior spaces.

**It should be noted that this study, and those like it, do not tell us how carbon dioxide negatively affects our cognition, just that it does, or at least it did on the tests they administered.


Post Script
Jun 2019, phys.org

Squalene, which is the greasy, grimous protective substance that once accumulated on your skin, interacts with ozone to produce secondary pollutants.

infographic image source

Notes
By Veronique Greenwood, The New York Times, May 6, 2019


Is CO2 an Indoor Pollutant? Direct Effects of Low-to-Moderate CO2 Concentrations on Human Decision-Making Performance. Usha Satish, Mark J. Mendell, Krishnamurthy Shekhar, Toshifumi Hotchi, Douglas Sullivan, Siegfried Streufert, and William J. Fisk. Environmental Health PerspectivesVol. 120, No. 12. 1 December 2012. https://doi.org/10.1289/ehp.1104789


Associations of Cognitive Function Scores with Carbon Dioxide, Ventilation, and Volatile Organic Compound Exposures in Office Workers - A Controlled Exposure Study of Green and Conventional Office Environments. Allen, Joseph G., Piers MacNaughton, Usha Satish, Suresh Santanam, Jose Vallarino, and John D. Spengler. 2015. “Associations of Cognitive Function Scores with Carbon Dioxide, Ventilation, and Volatile Organic Compound Exposures in Office Workers: A Controlled Exposure Study of Green and Conventional Office Environments.” Environmental Health Perspectives 124 (6): 805-812. doi:10.1289/ehp.1510037.

We simulated indoor environmental quality (IEQ) conditions in “Green” and “Conventional” buildings and evaluated the impacts on an objective measure of human performance: higher-order cognitive function.

On average, cognitive scores were 61% higher on the Green building day and 101% higher on the two Green+ building days than on the Conventional building day (p < 0.0001).

Cognitive function scores were significantly better under Green+ building conditions than in the Conventional building conditions for all nine functional domains.


W. J. Fisk. Indoor Air - International Journal of Indoor Environment and Health. 06 July 2017. https://doi.org/10.1111/ina.12403

There is compelling evidence, from both cross‐sectional and intervention studies, of an association of increased student performance with increased ventilation rates.

The net annual costs, ranging from a few dollars to about 10 dollars per person, are less than 0.1% of typical public spending on elementary and secondary education in the United States.

Saturday, August 19, 2017

Local Odor Vocab



Curren's SCAQMD Urban Odor Dictionary

You’re looking at a smell network based on the work of UCLA post-grad named Jane Curren. She took all the words used in odor complaints in southern California, and found the source of those complaints. These odor sources can be anything from a hidden garbage dump to a local restaurant. The size of the blue nodes doesn’t indicate smelliness; it indicates more descriptors. Restaurants have more descriptors because they have 1. More people near them and 2. A greater diversity of things that smell. (I’m guessing this.) What this chart does show is the most common odor complaints in the middle of the cluster – we smell burnt things a lot. Also rotten eggs/sulfur/natural gas.

Below, Curren went further and found the specific chemical source of these smells, and I listed them below. Next time you smell something funny, check this list. (And the next time you’re in New Jersey, take a tour of the New Jersey Turnpike mobile museum of olfactory delights, you’ll smell firsthand many of the odors on this list!)

Curren's Urban Odor Lexicon
               
Descriptor                           Odorant
solvent                                 2-butanone
petroleum                          2-methyl-1-propene
pungent                               2-pentanone
sweet                                   2-pentanone
lemon                                   acetaldehyde
alcohol                                  acetaldehyde
acrid                                      acrolein
pungent                               ammonia
sweet solvent                   benzene
sweet                                   dichloromethane
decayed cabbage             ethyl mercaptan
pungent                               formaldehyde
rotten egg                           hydrogen sulfide
woody                                  m-cresol
resinous                               m-cresol
medical                                                m-cresol
woody                                  o-cresol
resinous                               o-cresol
medical                                                o-cresol
woody                                  p-cresol
resinous                               p-cresol
medical                                                p-cresol
medical                                                phenol
sweet                                   phenol
irritating                               propanal
fruity                                     propanal
empyreumatic                  pyridinec
irritating                               sulfurdioxide
aromatic                              toluenec
fishy                                      trimethylamine
pungent                               trimethylamine
sweet                                   acetone
minty                                    acetone
sweet solvent                   benzene
woody                                  cresol
resinous                               cresol
medicinal                             cresol
sour                                       dimethyl disulfide
onion                                    dimethyl disulfide
decayed cabbage             dimethyl sulfide
decayed cabbage             ethyl mercaptan
garlic                                      ethyl mercaptan
aromatic                              ethylbenzene
pungent                               formaldehyde
rotten eggs                         hydrogen sulfide
skunk                                    i-propyl mercaptan
sour                                       methyl mercaptan
garlic                                      methyl mercaptan
decayed cabbage             methyl mercaptan
skunk                                    n-butyl mercaptan
skunk                                    n-propyl mercaptan
medicinal                             phenol
sweet                                   phenol
irritating                               propanal
sweet                                   p-xylene
sharp                                     thiophene
skunk                                    thiophene
rubber                                  toluene
moth balls                           toluene
aromatic                              1,2,4-trimethylbenzene
aromatic                              1,3,5-trimethylbenzene
vinegar                                 acetic acid
sour                                       acetic acid
chemical                              acetone
sweet                                   acetone
acrid                                      acrolien
pungent                               ammonia
sweet                                   a-pinene
pine                                       a-pinene
sweet solvent                   benzene
malty                                     butanal
burnt                                     butanal
rancid                                    butyric acid
sour                                       butyric acid
perspiration                       butyric acid
fruity                                     butyl acetate
dead body                          cadaverine
disagreeable sweet        carbon disulfide
almond                                 chlorobenzene
sweet                                   chloroform
ethereal                               chloroform
pungent                               crotonaledehyde
gasoline                               decane
ethereal                               dichloromethane
sour                                       dimethyl disulfide
onion                                    dimethyl disulfide
decaying vegetation       dimethyl sulfide
aromatic                              ethylbenzene
oily                                         heptanal
musty                                   heptanal
woody                                  heptanal
fatty                                      hexanal
green                                    hexanal
rotten egg                           hydrogen sulfide
sharp                                     isopropyl benzene
aromatic                              isopropyl benzene
sharp                                     cumene
aromatic                              cumene
lemon                                   limonene
decayed cabbage             methyl mercaptan
moth balls                           naphthalene
tar                                          naphthalene
sweet                                   m-xylene
gasoline                               octane
sweet                                   o-xylene
pungent                               pentanal
sharp                                     propanal
vinegar                                 propanoic acid
sour                                       propanoic acid
sweet                                   p-xylene
solvent                                 styrene
rubber                                  styrene
sweet                                   tetrachloroethene
rubber                                  toluene
moth balls                           toluene
sweet                                   tricholoroethane
fishy                                      trimethylamine
fecal                                      valeric acid
sour                                       valeric acid
sweet                                   vinyl acetate

Suffet and Rosenfeld's Urban Odor Lexicon
*much of Curren’s work came from Suffet and Rosenfeld, so I added their leftover terms here

Descriptor                           Odorant
Coffee                                  Furfruryl Thiopropionate
earthy                                   Geosmin
musty                                   2-Methyl isoborneol
moldy                                   2,4,6-Trichloroanisole
grassy                                   Cis-3-hexen-1-ol
dead animal                       Putresine
rotten vegetable              Dimethyl Trisulfide
fishy                                      Dimethyl Amine
fishy                                      Methyl Amine
plastic                                   Methyl Methacrylate
fecal                                      Indole
manure                                  Skatole
burnt                                     Guiaicol

Primary document: Curren, J. 2012. Characterization of Odor Nuisance. UCLA.

Supporting document: Suffet, I.H., and P.E. Rosenfeld (2007). The Anatomy of Odour Wheels for Odors of Drinking Water, Wastewater, Compost and the Urban Environment, Water Science and Technology 55(5), 335-344.

Research note: The descriptor names come from the above source and supporting documents, whereas the odor causing compounds were matched against varying sources which will not be listed here; see instead the source document for those references

Friday, July 28, 2017

On Odors and Air Quality



Forget Beijing, walk down the street in New York City and you will see people wearing facemasks like it’s cool. Actually, it is kind of cool, but it is really sad when you think about it. It’s also pretty sad because these facemasks will do mostly nothing to help your exposure to air pollution. What you really want is a NIOSH-Approved N95 Particulate Filtering Facepiece Respirators.

Air quality should be a big deal at this time of year. Not sure where you’re reading this from, but here in New Jersey, or perhaps the greater Northeast, summer brings with it daily air quality alerts. This is where you can’t breathe too much during the hours of 11am and 11pm. Mostly these alerts have to do with ozone, which is good when it’s up in the air blocking UV rays, but not so good when it's at ground level being inhaled by you.

There are plenty of other pollutants in our air, and those living in a metropolitan area should know about these things. As will be repeated below, air pollution is the world’s largest single environmental health risk.

While I was reading a great article about a massive data-fueled smell map, I came across this passage, and figured it’s good enough on its own to put here, because it makes a really important distinction between odor and air pollution.

From the article “Smelly Maps: The Digital Life of Urban Smellscapes,” in their methodology section, about the air quality of streets and how it effects their data:

“The olfactory experience of a city is inevitably influenced also by the quality of the air, measured by the amount of pollutants that are emitted in the atmosphere by several human activities. It is useful to clarify the differences between air pollutants and odors. Air pollutants are chemicals that, when released into the air, pose potential harm to human and environmental health. These chemicals may or may not be detected through the human senses (McGinley, Mahin, and Pope 2000). Some air pollutants have odors (e.g., benzene has a sickly sweet odor) while others, such as carbon monoxide, cannot be detected through the senses of smell. Air pollution is the world’s largest single environmental health risk, being the cause of one in eight of the total premature global deaths, according to the World’s Health Organization.” http://www.who.int/mediacentre/news/releases/2014/air-pollution/en/

This goes on to list the handful of pollutants that are measured in cities: carbon monoxide, nitrogen oxides, ozone, particulate matter at both 10 and 2.5 micrograms, and sulfur dioxide.

Later, in another section, the authors mention this, which gives us an inkling that odor detection and air pollution detection could become good friends:

“ Barcelona is predominantly characterized by smells related to food and nature, while London is characterized by smells related to traffic emissions and waste. As The Economist puts it: “In 2013 the annual mean concentration of NO2 on Oxford street was one of the highest levels found anywhere in Europe.” (The Economist 2015).

One way to detect an area where local, point-source air pollution might be a problem is to look for areas with less nature. The authors of this study found that many odors were complementary, so that odors of “nature” were not found near odors of “emissions” (i.e., pollution)

Before closing I should mention that odors as co-pollutants can indicate pollution levels high enough to cause averse health effects. In a dissertation on the subject of urban odors, the author gives examples of a natural gas facility emitting benzene and a pig farm emitting H2S. In neither case did the pollutant itself smell, but the co-pollutants were enough to start an investigation.
-Curren, J. 2012. Characterization of Odor Nuisance. UCLA.

Notes:
McGinley, C.; Mahin, T.; and Pope, R. 2000. Elements of Successful Odor/Odour Laws. In WEF Odor/VOC 2000 Specialty Conference.
The Economist. 2015. The big smoke. Britain needs to do more to clean up its dirty air. January 10th.

Primary Source:
Quercia, Daniele, Rossano Schifanella, Luca Maria Aiello, and Kate McLean. 2015. “Smelly Maps: The Digital Life of Urban Smellscapes.” In Proceedings of the Ninth International AAAI Conference on Web and Social Media (ICWSM 2015). Palo Alto, CA: AAAI Publications. 327-336. Accessed November 28, 2016. http://www.aaai.org/ocs/index.php/ICWSM/ICWSM15/paper/view/10572.

Full pdf:

Post Script:
The Evolution of Face-mask Fashion, bjournal.co, Dec 2015.

Image source: link